Page 63 - 6641
P. 63

hydroxide is formed.  The contents of the test tube with Cu
                 (OH)  2 are poured into three test tubes and each of them add:
                 a)  in  the  first  2-3  drops of  ethanol  b)  in  the  second  -  2-3
                 drops of 1,2-ethanediol (ethylene glycol) c) in the third  - 2-
                 3 drops of 1,2,3-propanetriol (glycerol) Shake the contents
                 of the test tubes and record the observations.

                      Typical reaction of phenols (hydroxybenzenes)

                 Most  compounds  containing  the  phenolic  nucleus  give  an
                 intense  blue or violet color when  interacting with  a  FeCl 3
                 solution.  In the case of phenol, the reaction of reaction with
                 FeCl 3 proceeds according to the following scheme:




                                                    H  O
                          OH                     O          O
                   6          +  FeCl                                +  3HCl
                                    3                  Fe
                                                  O          O
                                                  H    O     H





                             3
                 Pour 2-3 cm  of 2% aqueous phenol solution  into the test
                 tube, add 2-3 drops of 1% solution of ferrum (III) chloride
                 and observe the change in the color of the reaction mixture.
   58   59   60   61   62   63   64   65   66   67   68