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1      ethane → 1,1-dichloroethane → ethin → ethanal
                    2      calcium carbide → ethin → benzene →
                          cyclohexane → methylcyclopentane
                    3      cyclohexane → benzene → nitrobenzene →?
                          bromonitrobenzene
                    4      methane → Ethin → chloroethene → 1,1-
                          dichloroethane
                    5      methane → ethin → benzene → nitrobenzene
                    6     heptane → methylbenzene →?  - chlorotoluene
                    7     calcium carbide → ethin → benzene →
                          methylbenzene
                    8      cyclohexane → benzene → bromobenzene →?  -
                          bromonitrobenzene
                    9      ethin → benzene → chlorobenzene →
                          methylbenzene → benzoic acid
                   10      pentane → isopentane → isoprene
                   11       benzoic acid
                   12      ethen → ethin → ethanal
                   13     calcium carbide → ethin → benzene →
                          chlorobenzene →?  - chloronitrobenzene
                   14      pentane → 1-chloropentane → 1,5-
                          dichloropentane → cyclopentane →
                          chlorocyclopentane
                   15      calcium carbide → ethin → benzene →
                          methylbenzene
                   16      cyclohexane → benzene → bromobenzene →?  -
                          bromonitrobenzene
                   17      ethin → benzene → chlorobenzene →
                          methylbenzene → benzoic acid
                   18      pentane → isopentane → isoprene → isoprene
                          rubber
                   19      ethen → ethin → nitrobenzene → D -
                          dinitrobenzene
                   20      methane → ethin → cyanotene → propenic acid
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