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replaced.    With  alcohols  form  esters,  under  the  action  of
                 water-absorbing substances - anhydrides, under the action of
                 ammonia  -  ammonium  salts,  which,  when  heated,  are
                 converted into amides.

                                            Progress

                      The  reaction  of  the  "silver"  mirror  -  a  characteristic
                 reaction to the aldehydes.
                       Aldehydes are easily oxidized when they interact with
                 an ammoniacal solution of an oxide argentum to form the
                 corresponding acids and metal argentum, which precipitates
                 on the glass surface in the form of a "silver mirror":


                          O                         O

                   CH C    + 2[Ag(NH) ]OH    CH C      +2Ag    + 4NH + 2HO
                                                                      2
                                                                 3
                        3          3 2          3
                          H                         OH

                                             етанова кислота
                      In  a  clean  tube,  washed  in  turn  with  10%  alkaline
                                                        3
                 solution and distilled water, pour 3-4 cm of 1% solution of
                 nitrate  argentum  and  add  5%  ammonia  solution  in  such  a
                 quantity  as  to  make  the  precipitate  formed  first  dissolve
                 first.  To the resulting ammonia solution [Ag (NH 3) 2] OH, 1
                   3
                 cm   of  1%  solution  of  aldehyde  (methanal  or  ethanal)  is
                 added and the mixture is carefully heated.
                      The reduction reaction of the aldehydes with cuprum
                 (II) hydroxide
                                                   3
                       In  a  test-tube  pour  0,5  cm   of  10  %  solution  of
                                            3
                 methanal or manalu, 3-4 cm of 10% sodium hydroxide and
                 added drops of 5% solution of cuprum (II) sulfate. Heat the
                 contents of the vial.
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