Page 35 - 6641
P. 35

The  isolated  ethen  is  passed  into  a  test  tube  with
                 bromine  water,  which  is  rapidly  discolored  due  to  the
                 addition  of  bromine  in  the  place  of  double  bond  with  the
                 formation of 1,2-dibromoethane:


                               CH    CH +   Br 2          CH 2  CH  2
                                  2     2
                                                          Br    Br

                                                    1,2-dibromoethane
                                                  1,2-dibromoethane


                      When  passing  ethane  through  aqueous  solution  of
                 potassium  permanganate,  the  violet  coloration  of  KMnO 4
                 gradually  disappears  and  a  brown  precipitate  of  MnO 2  is
                 formed,  indicating  the  oxidation  of  the  ethane  by  the
                 reaction:


                                        4
                                                                    2
                    3 CH CH + 2KMnO +   HO        3 CH CH +2 MnO   +  KOH
                                          2
                                                     2
                                     4
                                                                 2
                                                          2
                        2
                            2

                                                   OH OH
                                                    1,2-ethanediol

                      If the ethen is ignited at the end of the gas-duct, then
                 there is
                      a  bright  flame.    The  reaction  of  ethen  burning  is
                 written as follows:

                      ethane  Н 2С=СН 2 + 3О 2 → 2СО 2 + 2Н 2О
                                 Н 2С=СН 2 + 3О 2 → 2СО 2 + 2Н 2О↑

                                  ethеne
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