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The name of the coordination complex containing the complex anion
consists of:
1) the name of the cation;
2) the names of the ligands and their number;
3) the names of the complexing agent with the suffix "-ate" and its
oxidation state (Roman numerals in parentheses)
Coordination numbers (the number of ligands) in the names of
coordination complexes are indicated by Greek numerals:
2 - di, 3 - try, 4 - tetra, 5 - penta, 6 - hexa (coordination number 1 in the title is
not indicated).
The names of the ligands are listed in alphabetical order and considered as a
whole.
For example:
+3
K 3[ Fe (CN) 6] potassium hexacyanferrate (III
↑ ↑ ↑ ↑
1 4 3 2
+4
Na[ Pt (NH 3)Br 5] sodium pentabromoamine platinate (IV)
↑ ↑ ↑ ↑ ↑
1 5 4 3 2
where 1, 2, ... 5 are the order of the components names of the coordination
complex.
The name of the coordination complex containing the complex cation consists of:
1) the names of the ligands and their amounts;
2) the names of the complexing agent and its oxidation state;
3) anion name
For example:
+2
[ Zn (NH 3) 4]SO 4 tetraammine zinc sulphate
↑ ↑ ↑ ↑
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