Page 80 - 6641
P. 80

Urea  is  a  typical  amide.    One  of  the  most
                 characteristic reactions is the formation of salts with mineral
                 and organic acids.
                       Concentrated  urea  solution  is  divided  into  two  test
                 tubes.
                       In the first test tube add 2-3 cm of concentrated urea
                 solution, add 2-3 cm of concentrated solution of nitric acid.
                 The contents of the test tube shake and cool.  After cooling
                 the reaction mixture, precipitate - ureanitrate:




                   H  N    C   NH + HNO           H  N   C     NH  HNO

                    2             2       3         2             2    3

                          O                              O         n .



                 Add  0,5-1  g  oxalate  acid  to  the  second  test  tube.    Ureid
                 precipitate (sour and medium, or cyclic composition):


                    H 2 N  C   NH + HNO  3        H 2 N  C     NH    HNO 3
                                  2
                                                                  2
                         O                               O
                                                                   n .


                            H
                        N   H                          NH    C   O
                                  H O  C  O
                 O   C         +                 O   C             + 2H O
                                                                       2
                                  H O  C  O
                            H                          NH    C   O
                        N
                            H


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