Page 51 - 6273
P. 51

,          ,        ,         etc.),  halogen  compounds  with  positive  oxidation

               states  ((НСlO,  НСlO 2,  НСlO 3,  НСlO 4),  nitric  acid  HNO 3,  and  nitrogen  oxides

               (N 2O 5,  NO 2,  N 2O),  concentrated  sulfuric  acid  H 2SO 4,  hydrogen  peroxide  H 2O 2,

               metal peroxides (Na 2O 2, KO 2, ВаО 2), The most important oxidants

               1     Atoms and molecules of active non-metals: Cl 2, F 2, Br 2, O 2, S;

                                                                                   +6
                                                                                        +5
                                                                                              +6
                                                                                                     +7
               2     Atoms of some elements with a high oxidation state  (S , N , Cr , Mn ).
                                                                                            +4    +4   -1
               3     Atoms of some elements with an intermediate oxidation state (S , N , О ).
               4     Oxidants in the industry: HNO 3, H 2O 2, K 2Cr 2O 7, O 2, O 3.

                     Oxidants in the laboratory: (H 2SO 4 (conc.),HNO 3, KMnO 4, KClO 3, H 2O 2,
               5
                     K 2Cr 2O 7).

               All oxidants contain in their composition an element whose electron configuration
                                                                                             2 6
               is not stable, but to the formation of a stable configuration of type s p  or another

                                                          5
                                                       2
                                                                                                     2 4
               type they lack one (for example, s  p  for Cl 2, Вr 2, І 2), two (for example, s p  for
               O 2) and up to four  electrons  Therefore, they attach electrons that are lacking, and
               reduce their oxidation state.

                     Reducing agents are substances that can transfer electrons. For example, the

                reducing agents are metals in the free state (especially alkaline and alkaline earth),

                Hydrogen,  and  Carbon.    Compounds  of  non-metals  with  the  lowest  levels  of

                oxidation,  that  is,  compounds  with        ,       ,      ,       ,       ,     ,        ,

                     etc. in their composition, belong to the reducing agents.

                     The most important reducing agents

                  1     Active metals:Na, Mg, Al.

                                                                                           -2
                                                                                                 -
                                                                                                    -
                                                                                                         -
                  2     Atoms of some nonmetals with a negative oxidation state (S , Cl , І , Br ).
                                                                                                     +3
                                                                                                +4
                                                                                                          -1
                        Atoms of some elements with an intermediate oxidation state (S , N , О ,
                  3
                                  +3
                            +2
                        Мn , Cr ).
                  4     Reducing agents in the laboratory: (Н 2S, Н 2SіO 3, HNO 2).
                  5     Reducing agents in industry: Hydrogen, Coal, CO, active metals.





                                                             51
   46   47   48   49   50   51   52   53   54   55   56