Page 53 - 6273
P. 53

The attachment of electrons (reduction)


                   +8e        +7e       +6e        +4e        +2e


                  -1        0           1         3        5         7
                 Сl        Сl         Сl         Сl         Сl        Сl


                        –1e         –2e       –4e       –6e        –8e
                                      Electron transfer (oxidation)




               Manganese  in  oxidation-reduction  reactions  detects  seven  oxidation  states,

               including six compounds for manganese:


                       Electron attachment (recovery)

                    +7e      +5e      +4e       +3e      +2e      +1e



                    0        2        3       4       5       6     7
                  Mn       Mn        Mn       Mn       Mn       Mn     Mn


                                  –1e      –2e       –3e      –4e    –5e

                        Electron transfer (oxidation)




                     The analysis of the given series of ions oxidation states, taking into account

               their electron configurations, shows that all elements, both metals and nonmetals,

               in the lowest oxidation state can only detect the reducing properties, since they can

               only transfer electrons, according to their electron configuration.  Thus, chloride

               ion  which  has  a  stable  electron  configuration  of  s2p6  can  no  longer  attach

               electrons.  Therefore,  in  reduction-oxidation  reactions  it  only  increases  the

               oxidation state and acts as a reducing agent.   The  metallic Manganese does  not

               have a stable electron configuration, but, having a metallic nature, it can also only

               transfer electrons.  Elements in the highest oxidation state can only take electrons

               and therefore act as oxidants.


                      Elements with intermediate oxidation state, depending on the conditions, may
               exhibit oxidative and reducing properties. For example, during the interaction of


                                                             53
   48   49   50   51   52   53   54   55   56   57   58