Page 119 - 4637
P. 119

These  muds  also  contained  organics  that  were  susceptible  to
           bacteria degradation.
                Many thousands of wells have been drilled successfully with
           proper use of quality  lignosulfonates and chrome lignites. Proper
           chemical treatment at the end of the well includes raising the pH,
           adding  a  biocide  and  a  dispersible  organic  amine  packer  fluid
           inhibitor if a fresh-water-base fluid is used. We understand that the
           casing had long, useful life when treated in this manner — while
           documentation is not easily available; sources indicate this as the
           trend. Relevant to the subject, Getty Oil Co. wrote a technical paper,
           published by NACE International, based on South Louisiana field
           case  histories,  mainly  on  high-strength tubulars  in  lignosulfonate
           systems. The lignosulfonate was not necessarily deemed the culprit
           from  the  field  case  histories  as  others  had  claimed.  This  operator
           realized the need for high pH and bacteria control. And the report
           showed  that,  with  proper  conditioning,  water-based  fluids  were
           more  protective  than  some  authors  of  this  period  realized.  For
           increased  temperature  stability  of  some  water-base  systems,
           gypsum and salt muds were treated with a group of new additives
           called "surfactants," including drilling mud surfactant (DMS) and
           drilling mud emulsifier (DME). And as usual, during this period,
           diesel  was  important  for  lubrication,  inhibition  and  fluid  loss
           control. Oil was chemically emulsified into the water-based fluids
           in  the  10  -  12%  by  volume  range.  The  resulting  oil-wet  film
           probably  played  an  important  part  in  corrosion  control  in  these
           systems. These fluids were used in the deep drilling trend in South
           Texas, with BHTs ranging over 450° to 500°F.

                                The 1970-1980 Period

                In the early 1970s, the low-pH KC1 / Polymer muds emerged
           as drilling fluids by choice. These fluids were found to minimize
           hole  problems  in  many  areas,  but  the  external  fluid  phase  could
           cause  corrosion.  Salt  content  is  near  that of  seawater  and  it  was

                                         118
   114   115   116   117   118   119   120   121   122   123   124