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The changing of internal energy is equal the work
U l , where l C T T U or
q q 1 2
R R RT P K K 1
l
l T T 2 ; q VP 1 1 P 2 V 2 ; q 1 1 2 ; (2.14)
l
1
q
k 1 k 1 k 1 P 1
The changing of the entropy is equal zero
s 0 .
2.5 Polytrophic process of gas
Polytrophic process — any process changing of thermodynamics co-ordinates which
is going at the constant value of specific heat.
n n 1 n 1
P 2 V T V T P n
1
For this process: ; 2 1 ; 2 2 (2.15)
P V T V T P
1 2 1 2 1 1
And work will be equal:
k 1
1 R RT P n
l VP P V T T 1 1 2
n 1 1 2 2 1 2 ; (2.14)
n 1 n 1 n 1 P
1
R
Heat for this process: q U l C V T T 1 T T 2 ; (2.15)
n
1
2
n 1
T 2
Change of entropy: s C n m ln ; (2.16)
T
1
C C
Polytrophic constant n n P ; (2.17)
C C
n V
n k
Polytrophic specific heat C n C V (2.18)
n 1
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