Page 20 - 6273
P. 20

(alkaline earth).  The general electron formula for the last energy level for these

                                                           2
               elements is described by the formula ns , where n is the period number.
                   The elements of the first and the second groups of main subgroups belong to

               the s-elements. The electrons of the elements III-VIII main subgroups fill in the p-

               sublevels.  The general electron formula for the last energy level for these elements

                                                    2
               is  described  by  the  formula  ns np    1  -  6 ,  where  n  is  the  period  number.    These
               elements are called p-elements. The electrons of the elements of the subgroups fill

               in the d-sublevel of the penultimate energy level (starting with the elements of the

                                                                          2
               fourth period).  The general formula for them is ns  (n-1) d          1  ÷  10 , where n is the
               period  number.    These  elements  are  called  d-elements.    For  example,  the  full

               electron formula for Cobalt is as follows:

                                      2
                               2
                                   6
                                             2
                                                 7
                            2
                                          6
                   27Co 1s 2s 2p 3s 3p 4s 3d
                   For d-elements, valence electrons are the last-level electrons and partially d-
               electrons of the penultimate energy level.
                                          th
                                                                                                       st
                   Starting with the 58  chemical element (after Lanthanum) and up to the 71  the
               electrons fill in the second external energy level of the f-sublayer.  These elements

               have similar physical and chemical properties, which is determined by the same
               structure  of the  last electron shells  of  their atoms.   They are called  lanthanides.


               The electron configuration of all lanthanides differs by the number of electrons at

               the inner 4f-sublayer - from zero in Lanthanum to the maximum possible number

               14  in  Lutetium.    For  example,  the  full  electron  formula  of  Gadolinium  is  as

               follows:


                                                                         1
                                                 10
                                                                     2
                                                                  6
                                                              10
                                                      6
                                                         2
                                      2
                                   6
                                                                            7
                               2
                                          6
                                             2
                            2
                   64Gd 1s 2s 2p 3s 3p 4s 3d 4р 5s  4d 5p 6s 5d 4f

                   For f-elements valence electrons are the last-level electrons and the d-electron
               of the penultimate energy level (underlined).  Therefore, lanthanides in compounds
               are  often  trivalent.    Similarly,  the  5f-sublevel  electrons  are  filled  with  elements
                                                             20
   15   16   17   18   19   20   21   22   23   24   25