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location of lower strength HAZ normal to the loading directions can
result in situations where fatigue cracks can sample more LBZ regions
thus increasing the possibility of brittle fracture. Recognising the
industry concern regarding LBZ, some steel companies have developed
LBZ free steels by alloy modifications to promote the austenite to ferrite
transformation and to prevent the bainite transformation.
5.2.2 Topside Materials
* The corrosivity of the production environments can be broadly
categorised as follows:
* 1/ Non-corrosive production: This includes conditions when corrosion
is not expected to occur. This includes conditions when the C02 partial
pressure is less than 5 psia and conditions when the pH value is higher
than 5.2 even if the C02 partial pressure is 30 psia. The pH value
depends mainly on alkalinity of water, acetate, temperature and C02
partial pressure. This could also include extremely corrosive conditions
where the corrosion is mitigated by the use of corrosion inhibitors.
* 2/ Production containing C02 : This corresponds to conditions where
the in situ pH value is lower than 5.2 or the partial pressure of C02
exceeds 30 psia. Under this environmental category, H2S can be present
as long as its partial pressure does not exceed 0.1 psia.
* 3/ Production containing H2S, or C02 and H2S : This corresponds to
production containing H2S with a partial pressure that exceeds 0.1 psia.
Under this environmental category, unlimited levels of C02 and
chlorides can also be present.
* 4/ Water injection: This is associated with seawater injection. In such a
case, the oxygen and chlorine contents are the important factors
governing the corrosivity. If produced water is reinjected, then the
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